molecular formula BaCl2 B8815432 Barium(2+) dichloride

Barium(2+) dichloride

Número de catálogo: B8815432
Peso molecular: 208.23 g/mol
Clave InChI: WDIHJSXYQDMJHN-UHFFFAOYSA-L
Atención: Solo para uso de investigación. No para uso humano o veterinario.
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Descripción

See also: Barium chloride (preferred).

Aplicaciones Científicas De Investigación

Analytical Chemistry

Gravimetric Determination of Sulfates

Barium dichloride is primarily used in analytical chemistry for the gravimetric determination of sulfate ions. In this process, a solution containing sulfate ions is treated with barium dichloride, resulting in the formation of barium sulfate, which precipitates out of solution. This reaction can be represented as follows:

BaCl2(aq)+SO42(aq)BaSO4(s)+2Cl(aq)\text{BaCl}_2(aq)+\text{SO}_4^{2-}(aq)\rightarrow \text{BaSO}_4(s)+2\text{Cl}^-(aq)

The precipitate is then filtered, dried, and weighed to determine the sulfate content in the original sample. This method is widely employed due to its accuracy and reliability in quantifying sulfate concentrations in various samples, such as water and soil .

Industrial Applications

Purification of Brine Solutions

In industrial settings, barium dichloride is utilized for the purification of brine solutions in caustic chlorine plants. It helps remove impurities that can affect the quality of chlorine produced . Additionally, it plays a role in the manufacturing of heat treatment salts used in metal processing.

Production of Pigments

Barium dichloride serves as a precursor for producing various pigments, including Lithol red and Red Lake C. These pigments are used in paints and coatings due to their vibrant colors and stability .

Oil and Gas Industry

In the oil and gas sector, barium compounds are essential for creating drilling muds. Barium sulfate, derived from barium dichloride, is commonly used to enhance the density of drilling fluids, aiding in the lubrication and cooling of drill bits during operations .

Environmental Applications

Water Treatment

Barium dichloride is employed in water treatment processes to remove sulfate ions from wastewater. Its ability to precipitate barium sulfate makes it effective in reducing sulfate levels to meet environmental regulations .

Case Study 1: Barium Chloride Toxicity Management

A recent case study highlighted the toxic effects of barium dichloride when ingested. The study documented a fatal case of barium chloride poisoning, emphasizing the importance of handling this compound with care due to its high toxicity levels. The report noted that while barium sulfate is safe for ingestion, other forms such as barium chloride are bioavailable and pose significant health risks .

Case Study 2: Industrial Use in Drilling Fluids

Another study focused on the application of barium sulfate derived from barium dichloride in drilling fluids for oil extraction. The research demonstrated that using barium-based drilling muds improved drilling efficiency and reduced equipment wear by providing better lubrication compared to traditional fluids .

Summary Table of Applications

Application AreaSpecific UseChemical Reaction/Process
Analytical ChemistryGravimetric determination of sulfatesBaCl2+SO42BaSO4+2Cl\text{BaCl}_2+\text{SO}_4^{2-}\rightarrow \text{BaSO}_4+2\text{Cl}^-
Industrial ProductionPurification of brine solutionsRemoval of impurities
Production of pigmentsSynthesis of Lithol red
Oil & Gas IndustryDrilling mudsEnhances density and lubricates drill bits
Environmental ScienceWater treatmentPrecipitation of barium sulfate

Propiedades

Fórmula molecular

BaCl2

Peso molecular

208.23 g/mol

Nombre IUPAC

barium(2+);dichloride

InChI

InChI=1S/Ba.2ClH/h;2*1H/q+2;;/p-2

Clave InChI

WDIHJSXYQDMJHN-UHFFFAOYSA-L

SMILES

[Cl-].[Cl-].[Ba+2]

SMILES canónico

[Cl-].[Cl-].[Ba+2]

Origen del producto

United States

Synthesis routes and methods I

Procedure details

Aqueous solutions of barium chloride (0.1 mol/1) and sulfuric acid (0.1 mol/1) were prepared by dissolving 24.675 gm of barium chloride (special reagent grade) and 10.100 gm of sulfuric acid (special reagent grade) into 1,000 gm of ion-exchanged water. The two solutions were heated at 30° C., followed by the reaction in the same manner as in Example 1 at pH 5.8 to obtain 19.5 gm of barium sulfate powder.
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Synthesis routes and methods II

Procedure details

Aqueous solutions of barium chloride (0.008 mol/1) and sulfuric acid (0.005 mol/1) were prepared by dissolving 1.974 gm of barium chloride (special reagent grade) and 0.505 gm of sulfuric acid (special reagent grade) into 1,000 gm of ion-exchanged water. Each solution was heated at 70° C. The barium chloride solution was added dropwise over a period of 10 minutes to the sulfuric acid solution, while the latter was stirred at 1,000 rpm by a U-shaped blade. After the addition, the mixture was stirred for a further 3 minutes to complete the reaction. The mixture was kept at pH 3.5 during the reaction. After cooling to the room temperature, the reaction mixture was filtered through a 5C filter paper, washed with water, and dried at 105° C. for 2 hours to obtain 1.12 gm of barium sulfate powder.
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